Irvine, Calif., Sept. 21, 2022 – Researchers at the University of California, Irvine and four national laboratories have devised a way to make lithium-ion battery cathodes without using cobalt, a mineral plagued by price volatility and geopolitical complications.
In a paper published today in Nature, the scientists describe how they overcame thermal and chemical-mechanical instabilities of cathodes composed substantially of nickel – a common substitute for cobalt – by mixing in several other metallic elements.
“Through a technique we refer to as ‘high-entropy doping,’ we were able to successfully fabricate a cobalt-free layered cathode with extremely high heat tolerance and stability over repeated charge and discharge cycles,” said corresponding author Huolin Xin, UCI professor of physics & astronomy. “This achievement resolves long-standing safety and stability…
